Uploaded by Clover the Clever 
2000x1000 PNG 3.19 MB
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Description
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Tags
+-SH safe2266981 +-SH artist:rizcifra100 +-SH princess celestia116977 +-SH princess luna121687 +-SH alicorn335766 +-SH pony1699479 +-SH friendship is magic4030 +-SH g42126360 +-SH my little pony: friendship is magic267611 +-SH adobe imageready257 +-SH cosmic love9 +-SH cute279960 +-SH cutelestia4437 +-SH duality5767 +-SH duo204609 +-SH duo female41750 +-SH eyes closed147782 +-SH feels1696 +-SH female1908392 +-SH first celestia image on derpibooru1 +-SH florence and the machine10 +-SH frown38466 +-SH hug39690 +-SH looking up25875 +-SH lunabetes4626 +-SH mare805687 +-SH royal sisters7479 +-SH s1 luna8864 +-SH sad32567 +-SH sadlestia103 +-SH sadorable1740 +-SH sibling love877 +-SH siblings25429 +-SH sisterly love665 +-SH sisters20402 +-SH sitting100039 +-SH song reference4353 +-SH spread wings105582 +-SH window16519 +-SH winghug4098
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Yup, image #3 is the first to feature Luna.
To tell the truth, this is the first Princess Celestia image posted on this site, and at the same time it was marked as the second Princess Luna image on the site’s history.