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nothing, he immunized to the poison joke, the reason we see him on this art purrr like a cat is by the fact he love poison joke, because the plant do like him, joke!
no he the one who create it and is not work on him and the poison joke a evolve in one 1000 years to be now part of nature, plus if he not the one who create it, is magic is too chaotic to let him be affected by the poison joke!
Twilight: What?
Dr. Egon Spengler: Don’t Expose Discord to poison joke.
Twilight: Why?
Celestia: It would be bad.
Applejack: Ah’m fuzzy on the whole good/bad thing. What do y’all mean, “bad”?
Celestia: Try to imagine all life as you know it stopping instantaneously and every molecule in your body exploding at the speed of light. Total protonic reversal.
Applejack: Right. That’s bad. Okay. All right. Important safety tip. Thanks, Princess.
“True Joy”