It’s the scene from chapter 5 of my MLP FIM cartoon crossover story Chaotic Order
 
It’s the scene where after Twilight secretly leaves Ponyville to search for Discord. She left a note telling her friends about her plan to try and talk to the Spirit of Chaos and Disharmony, however, Spike burned the note. :XD: While all of Equestria as well as their friends outside the kingdom run crazy with trying to find Twilight because they assume Discord kidnapped her, Twilight’s got to deal with her thought son what she really thinks of Discord.
 
She wants to be nice to him, yet on the other hand she doesn’t want to find herself played a fool again. And I’m sure you guys wanted to see what she looked like in her so-called ‘battle armor’. :XD:
 
 
Twilight let out a tired sigh as she kept walking, her bag feeling heavier with every step. She had been traveling all night since she left Ponyville, and by now it felt like the afternoon. She was exhausted beyond belief, but she felt she needed to keep going.
 
Wherever she was going.
 
Her surroundings were completely new to her, despite it was all a forest of trees and nature. But it definitely wasn’t the Everfree Forest, that was far away by now…
 
Twilight breathed out heavily before stopping by a nearby tree and placed her bag down. She laid against the tree, the shade giving her comfort.
 
“What am I doing?” She suddenly asked aloud, gazing up at the blue sky. “Oh, maybe I should have planned better!”
 
She wondered if the others had found her note by now. Oh, how worried she was to imagine their expressions of disbelief to realize she was going to take on Discord all by herself with only her element as her weapon!
 
Was she even going to find him?
 
“What was I thinking?” Twilight muttered to herself, placing her face in her hooves in despair. “Where would Discord be in all of this? He could be hundreds of miles away by now and still going!”
 
“Or seconds away and still close to you.”
 
Twilight let out a frightened yelp but turning her head in all directions, wondering where that voice came from. Suddenly, something popped out from high above the tree was she leaning against and it stretched out for her eyes to meet red and gold ones.
 
“Discord!” Twilight exclaimed.
 
“Hello, Twilight Sparkle,” he chuckled before he flew down from the tree and stood before her. “My, you look exhausted…” He observed her tired state. “You look like you just went through a day long marathon.”
 
“It’s been a marathon since you came back,” Twilight muttered, her eyes nearly hiding the glare on her face.
 
“Hmm, you don’t seem to be in a happy mood…” He said as he leaned his face closer to hers to gaze at her curiously. “Are you upset?”
 
“Upset?” She demanded angrily, startling him a bit. “You suddenly pop back, saying you were never encased in stone, shower others with your so-called gifts, and you ask me if I’m upset?”
 
Discord leaned back, raising an eyebrow at her. “Well…are you?”
 
Twilight let out a frustrated shout, stamping her hooves against the ground. Discord merely watched her, slightly confused yet amused.
 
“I take it has a lot to do with me?” He asked.
 
Twilight growled, barring her teeth in fury. “It has everything to do with you!” She shouted, pointing a hoof at him.
 
Discord was a little taken aback by her accusation, but he remained in place. “Look, I know my entrance was a little surprising, and, of course, there’s having turned Ponyville into the chaos capital of the world…”
 
“Of course, there’s that!” Twilight spat. “You…you…jerk!” She shouted angrily at him.
 
“I had a feeling you’d call me that,” He rubbed the back of his neck nervously.
 
“Not just a jerk!” Twilight grunted. “You thief! You liar! You…you…” She let out an angry sigh. “You non-stone numbskull!”
 
“Okay, that’s pushing it a little…” Discord said with slight disapproval. His eyes softened as he gazed at Twilight. “My dear, why are you even here if you think I’m some ‘non-stone numbskull’?”
 
“Why else?” She spat. “To make sure you don’t harm my friends!”
 
Before he could say anything, Twilight reached into her bag and took out various things. He simply watched as the unicorn combined them all together: a football helmet, a life-jacket, and combat boots.
 
Twilight glared at him as she slipped the helmet over her with her magic. As soon as she was done, she held her ground, as if ready to attack Discord any moment.
 
The Draconequus did his best not to laugh as Twilight stood before him. She looked so funny in her safety attire!
 
“I’m ready for you, Discord…” She growled. “And I’ll fight you, whether or not you take my horn again!”
 
Discord’s smile disappeared as he gazed at her with confusion. “Come now, Twilight, when was the last time I have ever taken your horn?”
 
Twilight’s eyes narrowed, her lips in a slight pout.
 
“Oh, you’re never going to let that go, huh?” Discord let out a nervous chuckle, rubbing the back of his neck. “Well, it was only for a short time…”
 
“And so is this meeting!” Twilight shouted as she stamped a hoof on the ground. “Just go, Discord!”
 
The Draconequus was slightly taken aback by her request. “Leave? But what about you?” He gazed at her attire to the bag she had carried.
 
“What about me?” Twilight demanded angrily. “Just…go!” She raged.
 
Discord simply raised an eyebrow at her, then he silently turned on his heel and casually walked away from her. However, his eyes still remained on her expression of rage as he put more distance between them.
 
“You know, Twilight Sparkle,” he said in a nonchalant yet slightly hurt tone, “I just wanted to make sure if you needed anything.”
 
Twilight shook her head, still glaring at him. “I don’t need anything from you.”
 
Discord let out a sigh before snapping his fingers and disappearing in a flash, leaving Twilight alone just as she wanted.
 
The unicorn held her angry gaze, regarding the area where Discord had just vanished. Her eyes were still narrowed, her lips were still in a pout.
 
Suddenly, her expression melted into one of despair as she lowered her head to the ground, her eyes drooping with complete guilt.
 
“Way to be friendly, Twilight…” She muttered to herself.
 

 

 
Twilight Sparkle and Discord from My Little Pony: Friendship is Magic (c) Lauren Faust